I had similar issue on my QNAP TS-210 and choose the risky way. If you are experiencing issues with your hard drive, its best to seek an Experienced Data Recovery Professional immediately. LaCie Data Recovery We offer a completely free, no-obligation 24 hour diagnostic Receive a file list, report and fixed-fee quote before proceeding LaCie. You may also consider "Clonezilla Live", "Hiren's BootCD", "gParted Live CD" and similar. This is for programs offering (or not) bootable version. Names (programs, tools and pieces of software) you may consider includes: "Acronis True Image Home", "Easeus Partition Master", "Partition Recovery" and "PowerQuest Drive Image". Or you can try any disk-repair tool available (even Windows version), if it offers an option of creating bootable CD with repair tools and accessing your damaged disk only from there (after system restart). My suggestion would be to either connect this disk to a computer having Linux system and try many disk-repair tools available there.
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You can't fix it from there and you surely can make things much worse (a good example is a system that claims that disk or partition full of data is empty). If this is true, you should NOT do anything with it under Windows. My shot is that, as with most NAS, it uses Linux Ext3 file system.